Nitrate reduction with bimetallic catalysts. A stability-addressed overview
نویسندگان
چکیده
• Pd-Sn and Pd-In catalysts have emerged as competitive alternative to Pd-Cu pair. An excess of promoter or noble metal provoke adverse effects on catalytic denitrification. Fouling leaching are considered the main causes catalyst deactivation. Regeneration processes been developed provide new life deactivated catalysts. Nitrate (NO 3 – ) pollution water bodies is a serious environmental problem worldwide. One major concerns about NO contamination lack cost-effective solutions for its removal from potential drinking resources. Current technologies, such ion exchange, reverse osmosis electrodialysis, produce reject with high concentration. Catalytic reduction an emerging technology, capable transforming into harmless N 2 . A critical issue achieve almost complete selectivity this last species so that final concentrations NH 4 + can fit stringent allowed limits. Numerous studies carried out evaluating activity bimetallic Catalyst deactivation by surface fouling, irreversible oxidation promoter, aggregation metallic particles remain challenge full-scale implementation nitrate reduction. Therefore, it necessary develop highly stable and/or effective regeneration. The existing literature respect reviewed hereby.
منابع مشابه
Bimetallic palladium-platinum dendrimer-encapsulated catalysts.
We report the synthesis, characterization, and catalytic activity of bimetallic palladium-platinum dendrimer-encapsulated catalysts (DECs). These materials are prepared by co-complexation of different ratios of palladium and platinum salts to the interior tertiary amines of fourth-generation, hydroxyl-terminated poly(amidoamine) (PAMAM) dendrimers. Chemical reduction of these composites yields ...
متن کاملSynthesis of Anchored Bimetallic Catalysts via Epitaxy
The development of thermodynamically stable supported bimetallic catalysts for high-temperature reaction is significant and highly desirable but remains a grand challenge. In this work, we report a novel approach that relies on the interaction of metal nanoparticles with the support material to form unique bimetallic nanoparticles, which epitaxially anchor onto the support surface. Such unique ...
متن کاملBimetallic palladium-gold dendrimer-encapsulated catalysts.
The synthesis, characterization, and catalytic properties of 1-3 nm-diameter bimetallic PdAu dendrimer-encapsulated catalysts are reported. Both alloy and core/shell PdAu nanoparticles were prepared. The catalytic hydrogenation of allyl alcohol was significantly enhanced in the presence of the alloy and core/shell PdAu nanoparticles as compared to mixtures of single-metal nanoparticles.
متن کاملStability of bimetallic Pd-Zn catalysts for the steam reforming of methanol
ZnO-supported palladium-based catalysts have been shown in recent years to be both active and selective towards the steam reforming of methanol, although they are still considered to be less active than traditional copper-based catalysts. The activity of PdZn catalysts can be significantly improved by supporting them on alumina. Here we show that the Pd/ZnO/Al2O3 catalysts have better long-term...
متن کاملUnderstanding and controlling nanoporosity formation for improving the stability of bimetallic fuel cell catalysts.
Nanoporosity is a frequently reported phenomenon in bimetallic particle ensembles used as electrocatalysts for the oxygen reduction reaction (ORR) in fuel cells. It is generally considered a favorable characteristic, because it increases the catalytically active surface area. However, the effect of nanoporosity on the intrinsic activity and stability of a nanoparticle electrocatalyst has remain...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Separation and Purification Technology
سال: 2022
ISSN: ['1873-3794', '1383-5866']
DOI: https://doi.org/10.1016/j.seppur.2022.120750